产品内容
本酶催化的反应为L-Valine + 2 [Reduced NADPH---Hemoprotein Reductase] + 2 O2 = (E)-2-Methylpropanal Oxime + 2 [Oxidized NADPH---Hemoprotein Reductase] + CO2 + 3 H2O (Overall Reaction);;(1a) L-Valine + [Reduced NADPH---Hemoprotein Reductase] + O2 = N-Hydroxy-L-Valine + [Oxidized NADPH---Hemoprotein Reductase] + H2O;;(1b) N-Hydroxy-L-Valine + [Reduced NADPH---Hemoprotein Reductase] + O2 = N,N-Dihydroxy-L-Valine + [Oxidized NADPH---Hemoprotein Reductase] + H2O;;(1c) N,N-Dihydroxy-L-Valine = (E)-2-Methylpropanal Oxime + CO2 + H2O,系统名称为L-Valine,[reduced NADPH---Hemoprotein Reductase]:oxygen Oxidoreductase (N-Hydroxylating),一种细胞色素 P-450(血红素-硫醇盐)蛋白。该酶催化 L-缬氨酸的两次连续 N-羟基化,这是木薯(Manihot esculenta)中生氰糖苷亚麻苦苷(linamarin)生物合成的关键步骤。两次羟基化的产物 N,N-二羟基-L-缬氨酸不稳定,经脱水和脱羧生成 (E) 构型的肟。目前尚不清楚脱羧是自发进行还是由酶催化。该酶也可以接受 L-异亮氨酸为底物,但活性较低。它不同于偏好 L-异亮氨酸的 EC 1.14.14.39(异亮氨酸 N-单加氧酶)。